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991.
Layered double hydroxides (LDHs) or hydrotalcite (HT)-like compounds with different kinds of metal ions (Mg-Al and Mg-Fe) in the brucite-like sheets were prepared and their adsorption properties were studied in the boron removal from aqueous solution under laboratory conditions. The hydrotalcites were synthesized by the coprecipitation method and were characterized by chemical analyses, X-ray diffraction (XRD), Fourier Transform infrared spectroscopy (FTIR) and specific surface area measurements (BET). The affinity of these materials with a mixture of B(OH)(3) and B(OH)(4)(-) was studied as a function of contact time, initial pH of the solutions, HT quantity and B concentration (adsorption isotherms). It was found that 120 min is enough time for the equilibrium state to be reached in boron adsorption. Boron removal was independent of the initial pH of the solutions because of the high buffering capacity of the LDHs. On the other hand, the adsorption capacity increases with increasing the adsorbent quantity. The adsorption isotherms, described by the Langmuir model, are of L-type, suggesting that B(OH)(4)(-) is adsorbed preferentially on HT-like materials. Besides, Mg-Al hydrotalcites showed higher adsorption capacity than Mg-Fe. We proposed that in Mg-Al hydrotalcites, the boron removal occurs by both adsorption on external surface and ion exchange, whereas for Mg-Fe it occurs only by surface adsorption. After treatment of a solution containing 5.2 mgBl(-1) with Mg-Al hydrotalcites the final boron concentration reached the recommended limit by WHO for drinking water (0.5 mgl(-1)). 相似文献
992.
Hawkins BA Diniz-Filho JA Bini LM Araújo MB Field R Hortal J Kerr JT Rahbek C Rodríguez MA Sanders NJ 《Ecology》2007,88(8):1898-1902
993.
Resource limitation of bacterial production distorts the temperature dependence of oceanic carbon cycling 总被引:2,自引:0,他引:2
Our view of the effects of temperature on bacterial carbon fluxes in the ocean has been confounded by the interplay of resource availability. Using an extensive compilation of cell-specific bacterial respiration (BRi) and production (BPi), we show that both physiological rates respond to changing temperature in a similar manner and follow the predictions of the metabolic theory of ecology. Their apparently different temperature dependence under warm, oligotrophic conditions is due to strong resource limitation of BP, but not of BRi. Thus, and despite previous preconception, bacterial growth efficiency (BGE = BPi/[BPi + BRi]) is not directly regulated by temperature, but by the availability of substrates for growth. We develop simple equations that can be used for the estimation of bacterial community metabolism from temperature, chlorophyll concentration, and bacterial abundance. Since bacteria are the greatest living planktonic biomass, our results challenge current understanding of how warming and shifts in ecosystem trophic state will modify oceanic carbon cycle feedbacks to climate change. 相似文献
994.
Gro Harlaug Olsen Michael L. Carroll Paul E. Renaud William G. AmbroseJr Ragni Olssøn JoLynn Carroll 《Marine Biology》2007,151(6):2167-2176
We assessed the effects of crude oil and drill cuttings on sediment oxygen demand (SOD) of marine benthic communities from
Arctic (Barents Sea) and temperate (Oslofjord) areas of the Norwegian continental shelf. Field-collected cores in both areas
were subjected to three different treatments: two concentrations of hydrocarbon-contaminated sediments, and drill cuttings
(DC). Cores were incubated for 21 days at 5°C (Barents Sea) and at 10°C (Oslofjord) during which SOD was measured five times.
We observed significantly higher SOD in the high oil concentration (HOC) and DC treatments compared to control cores from
the Arctic, but not in the temperate Oslofjord. No difference was observed between the low oil concentration (LOC) and control
at either location. The clear differences in the response of Arctic benthic communities to petroleum compounds compared to
temperate benthic communities is likely related to differences in community structure, sensitivity of individual taxa to petroleum-related
compounds and different contamination history of the two study areas. 相似文献
995.
Health risk assessment maps for arsenic groundwater content: application of national geochemical databases 总被引:3,自引:0,他引:3
This investigation assesses the feasibility of calculating and visualizing health risk estimates from exposure to groundwater
contaminated with arsenic (As) using data from national geochemical databases. The potential health risk associated with As-contaminated
groundwater was assessed based on an elaboration of existing geochemical data in accordance with accepted methodological procedures
established for human health risk assessment (U.S. Environmental Protection Agency methodology). A screening analysis approach
was used for estimating the contribution of As to the total chronic health risk from exposure to groundwater contaminated
with potentially toxic elements, including As, Ba, Cd, Cu, Hg, Pb, Sb, Se and Zn, and the results indicate that As contributes
significantly (>50%) to this total health chronic risk in about 10% of Slovak territory. Based on the calculation of the
potential risk level by exposure modelling, increased chronic as well as carcinogenic risk levels (medium to high) were documented
in approximately 0.2 and 11% of the total Slovak area, respectively. The areas characterized by high health risk levels are
mainly those geogenically contaminated. High and very high carcinogenic risk was determined in 34 of 79 districts and in 528
of 2924 municipalities. 相似文献
996.
Effects of paternal care on reproductive success in the polygynous spotless starling Sturnus unicolor 总被引:2,自引:0,他引:2
J. Moreno José P. Veiga Pedro J. Cordero Eduardo Mínguez 《Behavioral ecology and sociobiology》1999,47(1-2):47-53
For males of socially polygynous avian species like the spotless starling, there may exist a trade-off between investing in
paternal care and controlling several nests. To determine how the intensity of paternal care affects reproductive success
per brood sired or expressed as the total number of young raised in all nests controlled by the same male, it is necessary
to manipulate paternal care. Testosterone (T) has been shown to depress the tendency for males to care for their young, and
induces them to acquire more mates. The effects of paternal care on reproductive success were studied by treating certain
male starlings with exogenous T and others with the antiandrogen cyproterone acetate (CA), and comparing the parental behavior
of T- and CA-males throughout the breeding season with that of controls. CA-males fed their chicks more during the first week
after hatching than T-males, with controls feeding at intermediate rates, both on a per nest basis and as total effort for
all nests controlled by the same male. Paternal feeding rates during the first week of chick life had a significant positive
effect on the number of fledged young. The hormone treatment significantly affected the number of chicks raised per nest,
CA-males having a higher breeding success per nest than T-males, and controls showing intermediate levels of success. There
was no significant effect of treatment on total reproductive success attained by males throughout the season. In the polygonous
spotless starling, the intensity of paternal care of young affects reproductive success per nest positively but not on a seasonal
basis.
Received: 6 February 1999 / Received in revised form: 30 June 1999 / Accepted: 11 July 1999 相似文献
997.
José A. Donázar Alejandro Travaini Olga Ceballos Alejandro Rodríguez Miguel Delibes Fernando Hiraldo 《Behavioral ecology and sociobiology》1999,45(1):55-65
Phenotype-limited interference models assume competitive asymmetries among conspecifics and unequal sharing of resources.
Their main prediction is a correlation between dominance status and patch quality: dominant individuals should preferentially
exploit better-quality habitats. We tested assumptions and predictions of the phenotype-limited interference model in Andean
condors (Vultur gryphus), a New World vulture with strong sexual size dimorphism (males are 30–40% heavier than females). We recorded searching birds
in habitats differing in quality: mountains and plains. We also observed scavenging behaviour at 20 sheep carcasses, and videotaped
5 of them. Intraspecific hierarchy at carcasses was based on size: males dominated females and, within each sex, older birds
dominated younger ones. Adult males and juvenile females occupied extreme positions in the feeding hierarchy. Aggression was
directed at those individuals belonging to lower hierarchical levels. In high-quality areas (mountains), more condors arrived
at carcasses. Juvenile females were more often observed searching in low-quality areas (plains), far from breeding areas and
main roost sites. GLM analyses of individual behaviour showed that the hierarchy did not influence time of arrival, but low-ranking
individuals spent more time at carcasses, especially if the number of condors at arrival was high. Additionally, low-ranking
condors spent less time feeding at carcasses when individuals of higher hierarchical levels were present. On the other hand,
the number of condors present had a positive effect on feeding rates of dominant individuals, probably because of a reduction
in individual vigilance. These results support most of the assumptions and predictions of the phenotype-limited distribution
model, although a spatial truncated distribution between phenotypes was not observed. Asymmetric feeding pay-off, unequal
parental roles and sexual selection constraints could favour sexual divergence in body size in Andean condors.
Received: 6 April 1998 / Accepted after revision: 11 July 1998 相似文献
998.
Kevin R. Foster Perttu Seppä Francis L. W. Ratnieks Peter A. Thorén 《Behavioral ecology and sociobiology》1999,46(4):252-257
Queen mating frequency was studied in the European hornet, Vespa crabro, by analyzing four DNA microsatellite loci in 20 workers from each of 14 nests. Queens were found to be predominantly singly
mated (9/14), although double (4/14) and triple mating (1/14) also occurred. For most multiply mated queens, paternity was
significantly biased with the majority male fathering on average 80% of the female offspring. The population-wide effective
mating frequency was therefore low (1.11), and sister-sister relatedness high (0.701 ± 0.023 SE). Low effective mating frequency
in Vespa, in combination with data from other vespines, suggests that high paternity frequency is derived in the group. Some problems
with the non-detection of fathers, where the queen was not sampled or shared alleles with males, are analyzed.
Received: 16 November 1998 / Received in revised form: 29 March 1999 / Accepted: 12 April 1999 相似文献
999.
Summary. The among-leaves allocation of DIBOA, a hydroxamic acid associated with plant resistance, in the shoot of rye (Secale cereale) was evaluated over the vegetative development of the plant. The appropriateness of using the concentration of secondary
metabolites, DIBOA in this case, as the parameter to evaluate defense allocation in plants is discussed. Both biological and
statistical arguments are put forward to suggest that allocation of chemical defenses should refer to absolute content and
not to concentration. Results showed that leaf age was significantly linked to leaf concentration of DIBOA, young leaves having
higher concentrations. In contrast, leaf content of DIBOA, our proposed currency of allocation, was not significantly higher
in younger leaves. Furthermore, a regression analysis showed that the DIBOA content of leaves was better explained by the
leaf relative biomass (proportion of shoot biomass) than by leaf biomass itself. It is suggested that, rather than leaf age,
leaf relative biomass is the major factor determining DIBOA allocation in rye shoots. It is proposed that studies addressing
within-plant defense allocation should use chemical defense content as the currency, emphasizing the major factors driving
this process and its underlying mechanisms. Likewise, it is proposed that studies aiming at characterizing optimal patterns
of plant defense should use chemical defense concentration as the currency, and be accompanied by evaluations of the actual
resistance against herbivores of the plant parts analyzed, together with the effect on plant fitness.
Received 19 February 1999; accepted 28 April 1999. 相似文献
1000.
Susana García-Alonso Rosa María Pérez-Pastor María Luisa Sevillano-Castaño 《Environmental science and pollution research international》1999,6(3):147-150
The focus of this study was to characterize the concentration levels of selected PCBs and compare them to compiled data in
order to contribute to the international database. The sampling site is located in the outskirts of Madrid and can be considered
an open urban area. 32 samples of air were taken from February 1998 to June 1998 by using a high volume air sampler. Glass
fiber filters and polyurethane foam (PUF) were used to collect the paniculate and gas phase material, respectively.
PUF plugs were Soxhlet extracted and filters were ultrasonically extracted by using pesticide-grade hexane and dichloromethane,
respectively. The cleanup procedure was carried out on a florisil column with hexane and hexane/dichloromethane as elution
solvents.
GC/MS in a selected ion monitoring mode was used for quantification and 29 selected PCBs congeners were analyzed. 相似文献